Scientific publications
* (Corresponding author)
Other affiliations: Centre National de la Recherche Scientifique · Laboratoire Interdisciplinaire des Environnements Continentaux · Université de Lorraine
Jean Mermoz Siéwé
Cyrill Joël Ngally Sabouang
Angélina Razafitianamaharavo
Other affiliations: Laboratoire Interdisciplinaire des Environnements Continentaux · Université de Lorraine
Fabien Thomas
Other affiliations: Laboratoire Interdisciplinaire des Environnements Continentaux · Université de Lorraine
ChemEngineering
The present study deals with the relation between crystalline order in kaolinites and their ability to intercalate DMSO. Raw clays and kaolinite–DMSO complexes are analyzed using FTIR, XRD powder diffraction and differential scanning calorimetry and thermogravimetric analysis (DSC-TGA). The crystallinity is accessed using the Hinckley index (HI) from the raw clays’ XRD patterns and the p2 factor from their FTIR spectra. The intercalation ratio is evaluated from XRD and compared among the samples. The thermal analyses show a decrease in the dehydroxylation temperature in the DMSO–kaolinite complexes, indicating a decrease in the interlayer cohesion that may be useful to improve the delamination of kaolinite. The analysis of the coherent scattering domain size in the raw and the DMSO-intercalated samples indicates that the ordering is not affected during the DMSO intercalation. From these results, it is deduced that DMSO intercalation is favored by an increased crystallinity, as revealed by the intercalation ratio from XRD and the DSMO release during DSC-TGA analysis.
